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If you are an Ambassador for the group you're browsing, you will have a few more options: adding and removing users.
Adding a user to the group
You can use the top section of the page to start typing a user name, then use the "Add" button to save and add the user to the group:
Starting with version 1.1, you can add multiple users to the group you're currently managing in a single click 
You will receive a notification and the user list will be updated once the user is successfully added:
Removing a group member
You can use the "Remove from group" action to remove a user from a group. A notification will confirm the removal have been done:
Exporting Users list
You can export the list of users in a group you're managing. All information on screen will be exported in one of those two formats:
CSV/Excel (UTF-8): This format is Comma Separated Value which is raw data and usually imported and used with Excel or technical tools.
HTML: A more visual view in a simple webpage (we know it's ugly now, we're working on a brand new view
)
Nominating Ambassadors
If Super Ambassadors feature is enabled, you can nominate other Ambassadors for the groups you're Ambassador of.
To do so, simply click on the "Nominate Ambassadors" link in the Group Browser:
A popup will show and you can nominate one or multiple Ambassadors by typing their name, username or email.
Checking who else is Ambassador
As an Ambassador, you can also check who else is Ambassador for a group by clicking on the "?" icon near the group name in the Group Browser:
Audit Logs Notice
Please note that all actions taken by Ambassadors are tracked in Jira's Audit Log.
those actions might also be tracked in Group ambassadors logs.
Jira administrators will be able to follow actions from the log for security reasons.